Ahmad Masarwa The Hebrew University of Jerusalem
The use of gem-bis-metalated-alkenes, i.e., vinyl gemdiboron-compound, as light-labile substrates is explored for the first time. The knowledge gained provided us with an in-depth understanding of the reactivity of novel radical intermediates of geminal-metalated ethane. This methodology can serve as the late-stage diversification of bioactive molecules and simple organic molecules in which it drives the synthesis of gemdiborylalkanes.
This is not the last version
download asset Ahmad Masarwa chemrxiv Dec.2019 A.pdf 1 MB [opens in a new tab] cloud_download
pdf : 1 MB