Organic Chemistry

Relay Cross Metathesis for the Ascent of the Terpenoids

Abstract

We report the design and implementation of a relay cross metathesis (ReXM) reaction for the ascent of the terpenoids in an iterative protocol using naturally occurring terpenoid building blocks. The method is used for the synthesis of a diterpene-benzoate macrolide of biogenetic relevance to the bromophycolide family of natural products.

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ChemRxiv_v1

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Relay Cross Metathesis for the Ascent of the Terpenoids ChemRxiv SI

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