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Synthesis of Vitisin A & D: Thermal Isomerization Enabled by a Persistent Radical Equilibrium

22 November 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The total synthesis of oligomer natural products derived from resveratrol has been achieved through a putative biogenetic bond migration from a presumed common intermediate in a divergent biosynthetic pathway.

Keywords

resveratrol
persistent radical
total synthesis

Supplementary materials

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Stephenson manuscript
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Now Published

Synthesis of Vitisins A and D Enabled by a Persistent Radical Equilibrium [opens in a new tab]
Kevin J. Romero, Mitchell H. Keylor, Markus Griesser, Xu Zhu, Ethan J. Strobel, Derek A. Pratt, Corey R. J. Stephenson journal article
Journal of the American Chemical Society , Volume 142, Issue 14
Online publication date: Mar 11, 2020

Version History

Nov 22, 2019 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.10294826.v1
D O I: 10.26434/chemrxiv.10294826.v1 [opens in a new tab]

Funding

National Institute of General Medical Sciences
R01GM121656
Enabling Elucidation of the Biological Activity of Resveratrol Natural Products with Synthesis
https://app.dimensions.ai/details/grant/grant.6617135 [opens in a new tab]

Author’s competing interest statement

No conflict of interest

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