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Transient Supramolecular Assembly by Programmable pH Cycles

09 October 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Transient self-assembly is a necessary step towards the development of life-like materials. Our approach allows to program pH-driven supramolecular assembly in the time domain with tailorable lag- and life-times, overcoming the limitations of previously described approaches and setting a new standard for active materials design.

Keywords

Clock reactions
Supramolecular assembly
Time domain
pH-Driven Reversible Self-Assembly
Perylene diimide
Cyclic esters
Formaldehyde clock

Supplementary materials

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Transient supramolecular assembly by programmable pH cycles
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Version History

Oct 09, 2019 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.9938105.v1
D O I: 10.26434/chemrxiv.9938105.v1 [opens in a new tab]

Author’s competing interest statement

There are no conflicts of interest.

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