Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Efficient Z-Selective Semi-Hydrogenation of Internal Alkynes Catalyzed by Cationic Iron(II) Hydride Complexes

16 September 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We describe here the application of the well-defined bench-stable cationic aminoborane complex as highly efficient pre-catalysts for the semi-hydrogenation of internal alkynes, 1,3-diynes and 1,3-enynes with molecular hydrogen under mild conditions.

Keywords

iron
hydrogenation
alkynes
deuterium incorporation

Supplementary materials

Title
Description
Actions
Title
Fe PNP AlH4 dimer
Description
Actions
Title
Fe PNP Alkyne hydrogenation ESI
Description
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Sep 16, 2019 Version 1

Version Notes

Version 1.0

Metrics

3,214
652
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.9821846.v1
D O I: 10.26434/chemrxiv.9821846.v1 [opens in a new tab]

Funding

Austrian Science Fund P29584-N28

Author’s competing interest statement

no conflict of interests

Share