Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Decarboxylative C–C and C–N Bond Formation via Ligand-Accelerated Iron Photocatalysis

13 September 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Through iron photocatalysis, a mild and effective protocol for the decarboxylative C–C and C–N bond formation has been achieved. The carboxylic acids readily underwent radical decarboxylation in the presence of Fe2(SO4)3 and di-(2-picolyl)amine with visible light irradiation. The resultant alkyl radicals then reacted with Michael acceptors or azodicarboxylates to furnish the adducts.

Keywords

Ligand-Accelerated
Iron Photocatalysis
Decarboxylative
C–C Bond Formation
C–N Bond Formation

Supplementary materials

Title
Description
Actions
Title
Supporting Information Fe
Description
Actions

Supplementary weblinks

Title
Description
Actions
Title
Description
Actions
View

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Decarboxylative C–C and C–N Bond Formation by Ligand‐Accelerated Iron Photocatalysis [opens in a new tab]
Guangshou Feng, Xiaofei Wang, Jian Jin journal article
European Journal of Organic Chemistry , Volume 2019, Issue 39
Online publication date: Oct 11, 2019

Version History

Sep 13, 2019 Version 1

Version Notes

The first version for Chemrxiv.

Metrics

4,003
1,143
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.9816950.v1
D O I: 10.26434/chemrxiv.9816950.v1 [opens in a new tab]

Funding

Natural Science Foundation of Shanghai (19ZR1468700)

Author’s competing interest statement

The authors declare no competing financial interest.

Share