Abstract
Sulfamides guide intermolecular chlorine transfer to gamma-C(sp3) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp3)-H bonds.
Supplementary materials
Title
2019-05-23 - Sulfamide chlorine-transfer SI - COMPLETE - V2
Description
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