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This content is a preprint and has not undergone peer review at the time of posting.
Abstract
Dihydroboration of a variety of carbodiimides using pinacolborane (HBpin) is achieved through commercially available tin(II) halides [SnBr2 (1) and SnCl2 (2)] as catalysts at room temperature (21 °C) with short reaction times (0.13 to 6 h).