Intermolecular Aminoallylation of Alkenes Using Allyl-Oxyphthalimide Derivatives: A Case Study in Radical Polarity Effects

05 July 2019, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A case study on the polarity effects of radical mediated intermolecular alkene aminoallylation is presented herein. This radical group transfer method pairs vinyl ethers with electronically deficient allyl-oxyphthalimide derivatives to give difunctionalized products while illustrating the guiding effects of polarity on this radical reactivity.

Keywords

radical chemistry
polarity effects
aminoallylation
O-atom transfer
phosphite

Supplementary materials

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Title
2019-07-03-AA-ChemRxiv-SI
Description
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