Organometallic Chemistry

Balancing Bulkiness in Gold(I) Phosphino-Triazole Catalysis

Abstract

A series of phosphino triazoles are disclosed, within which, the phosphorus atom is appended by one, two or three triazole motifs. Gold(I) chloride complexes of the synthesised ligands were prepared and analysed by techniques including single crystal X-ray diffraction structure determination. SambVca (2.0) was used to determine percentage buried volumes. The effectiveness of these gold(I) chloride complexes to serve as precatalysts for alkyne hydration were assessed.

Content

Thumbnail image of 01 Main Bulk balancing.pdf
download asset 01 Main Bulk balancing.pdf 2 MB [opens in a new tab]

Supplementary material

Thumbnail image of 00 GA2.jpg
download asset 00 GA2.jpg 0.44 MB [opens in a new tab]
00 GA2
Thumbnail image of 02 ESI Bulk balancing.pdf
download asset 02 ESI Bulk balancing.pdf 9 MB [opens in a new tab]
02 ESI Bulk balancing