Physical Chemistry

Real-Time Optical and Electronic Sensing with a β-Amino Enone Linked, Triazine-Containing 2D Covalent Organic Framework

Abstract

Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant β-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH3 vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.

Version notes

Under review in Nature Communications NCOMMS-19-04469A.

Content

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Supplementary material

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20190409 PBHP-TAPT COF SI
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Raw Data-20190410
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Source Data-20190410
Thumbnail image of Activation-deactivation for HCl and NH3 vapours (Optical responce).mp4
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Activation-deactivation for HCl and NH3 vapours (Optical responce)