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Metal-Organic Frameworks (MOFs) as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

08 April 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Systematic investigation of combustion energies for popular metal-organic frameworks (MOFs) reveals energy content comparable to conventional energetic materials and can be further modified and dine-tuned by polymorphism and isostructural ligand replacement to yield materials with energy densities comparable to Diesel or kerosene.

Keywords

metal-organic frameworks
fuels
energy
combustion
propellant
structure
zeolitic imidazolate frameworks
energy density

Supplementary materials

Title
Description
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Title
ChemRxiv SI 1
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Now Published

Metal–Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs [opens in a new tab]
Hatem M. Titi, Mihails Arhangelskis, Athanassios D. Katsenis, Cristina Mottillo, Ghada Ayoub, Jean-Louis Do, Athena M. Fidelli, Robin D. Rogers, Tomislav Friščić journal article
Chemistry of Materials , Volume 31, Issue 13
Online publication date: Jun 03, 2019

Version History

Apr 08, 2019 Version 1

Version Notes

This is version 1.

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.7962851.v1
D O I: 10.26434/chemrxiv.7962851.v1 [opens in a new tab]

Funding

NSERC E. W. R. Steacie Fellowship (SMFSU 507347-17)
NSERC Discovery Grant (RGPIN-2017-06467)
NSERC Strategic Grant (STPGP 521582-18)
Canada Research Excellence Chair program (grant 240634)
AFOSR (FA9550-14-1-0306)

Author’s competing interest statement

CM and TF are co-founders, and RDR is the scientific advisory board member of ACSYNAM, Inc., which has provided one of the materials for the study.

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