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Copper-Catalyzed Hydrocarboxylation of Allenes

19 March 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The addition of carboxylic acids to allenes was performed for the first time with copper catalysis. The hydrocarboxylation reaction is totally regio- and stereoselective, ligand-free and used catalytic amounts of copper and base.

Keywords

copper-catalyzed
Hydrocarboxylation
allenes
Carboxylic acids
Homogeneous Catalytic Reactions
hydrofunctionalisation

Supplementary materials

Title
Description
Actions
Title
Abstract hydrocarboxylation
Description
Actions
Title
Supporting Information Hydrocarboxylation
Description
Actions

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Version History

Mar 19, 2019 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.7862456.v1
D O I: 10.26434/chemrxiv.7862456.v1 [opens in a new tab]

Funding

Région Languedoc-Rousillon
ANR CD2I CuFeCCBond
IUF Institut Universitaire de France

Author’s competing interest statement

no conflict of Interest

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