Catalysis

Catalytic Hydrogenations with Cationic Heteroleptic Copper(I)/N-Heterocyclic Carbene Complexes

Johannes F. Teichert Technische Universität Berlin

Abstract

A new heteroleptic cationic copper(I) complex bearing two N-heterocyclic carbene (NHC) ligands has been prepared. In situ, a Cu–O-bond can be generated which enables the complex to catalytically activate H2. The resulting complex shows activity in catalytic chemo- and stereoselective alkyne semihydrogenations as well as conjugate reductions of enones.

Content

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Supplementary material

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Teichert Cationic complexes SI