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Fe-N-C Artificial Enzyme: Activation of Oxygen for Dehydrogenation and Monoxygenation of Organic Substrates under Mild Condition and Cancer Therapeutic Application

04 June 2018, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Developing highly efficient artificial enzymes that directly employ O2 as terminal oxidant has long been pursued but has rarely achieved yet. We report Fe-N-C has unusual enzyme-like activity in both dehydrogenation and monoxygenation of organic substrates with ~100% selectivity by direct using O2.

Keywords

Artificial Enzyme
Metal-Nitrogen-Carbon Catalyst
Aerobic Oxidation Reactions
Dehydrogenation
Monoxygenation
Direct Use of Molecuar Oxygen
cancer treatments

Supplementary materials

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SI.2018.06.04
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Now Published

Fe–N–C Artificial Enzyme: Activation of Oxygen for Dehydrogenation and Monoxygenation of Organic Substrates under Mild Condition and Cancer Therapeutic Application [opens in a new tab]
Fei He, Li Mi, Yanfei Shen, Toshiyuki Mori, Songqin Liu, Yuanjian Zhang journal article
ACS Applied Materials & Interfaces , Volume 10, Issue 41
Online publication date: Sep 24, 2018

Version History

Jun 04, 2018 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.6427643.v1
D O I: 10.26434/chemrxiv.6427643.v1 [opens in a new tab]

Author’s competing interest statement

No conflict of interest

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