Endgroup and Sidechain Functionalization of Surface-Initiated ROMP Thin Films: Progress Towards ROMP-Based Molecular Wires

07 March 2018, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A set of experiments in surface-initiated ring-opening metathesis polymerization, including end-functionalization of growing brushes and contact angle/cyclic voltammetry measurements. We report preparation and CV of two different conjugated polymer films, and several endgroup and sidechain functionalization experiments using cross-metathesis and active ester substitution.

Keywords

metathesis
romp
si-romp
edot
end-functionalization
cyclic voltammetry
oxidative polymerization
nhs ester
norbornene
ferrocene
electron transfer
polyacetylene

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