A New Atomic Deformation Constraint Rule and Its Application

weicheng zeng

doi:10.26434/chemrxiv.5857875.v1

Inorganic Chemistry

Search within Inorganic Chemistry

A New Atomic Deformation Constraint Rule and Its Application

06 February 2018, Version 1

This is not the most recent version. There is a

newer version

of this content available

Working Paper

weicheng zeng

Show author details

This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A new principle of steady state of atoms in heteronuclear diatomic molecules based on constraint rule is proposed. Each atom in a heteronuclear diatomic molecule is described by three parameters a, b and ζand the atoms are the most stable when the value ζa/b is constant(2.601824). This model has one free parameter which was fitted by the graphical method.The calculated dissociation energy are in good agreement with the known experimental values.

Keywords

Isoelectronic ionization energy

graphical method

New physical constant

Critical points

constraint rule

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here .

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.