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(2-Fluoroallyl)pyridinium Tetrafluoroborates: Novel Fluorinated Electrophiles for Pd-Catalyzed Allylic Substitution
preprintsubmitted on 23.03.2021, 10:51 and posted on 24.03.2021, 10:33 by Angelina Yu. Bobrova, Maxim Novikov, Yury V. Tomilov
An efficient two-step approach to 2-fluoroallyl amines was developed that involves the synthesis of (2-fluoroallyl)pyridinium tetrafluoroborates from readily available gem-bromofluorocyclopropanes and the application of the former as novel and stable 2-fluoroallyl electrophiles for Pd-catalyzed allylic substitution
(Fluoroallyl)pyridinium tetrafluoroborates: a novel type of building blocks for palladium-catalyzed fluoroallylation in the synthesis fluoroalkene-based biologically active compounds and peptidomimetics
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