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(2-Fluoroallyl)palladium Complexes as Intermediates in Pd-Catalyzed Tsuji-Trost 2-Fluoroallylations: Synthesis and Reactivity

preprint
submitted on 09.04.2020 and posted on 10.04.2020 by Angelina Yu. Bobrova, Maxim Novikov, Igor A. Mezentsev, Yury V. Tomilov
The first examples of (2-fluoroallyl)palladium complexes were synthesized, isolated and characterized including chloride dimers, neutral chloride and ionic triflate complexes bearing PPh3 or SPhos as the ligands. Preliminary reactivity patterns indicating strong dependence of the chemoselectivity on "hardness" of the nucleophile and the ligand type were studied.

Funding

(Fluoroallyl)pyridinium tetrafluoroborates: a novel type of building blocks for palladium-catalyzed fluoroallylation in the synthesis fluoroalkene-based biologically active compounds and peptidomimetics

Russian Science Foundation

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History

Email Address of Submitting Author

manovikov90@mail.ru

Institution

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Country

Russian Federation

ORCID For Submitting Author

0000-0002-7259-494X

Declaration of Conflict of Interest

No conflicts of interest

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