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Zero-Valent Pd Atoms Anchored on Polyoxometalate for Low Temperature Hydrodeoxygenation

preprint
submitted on 18.12.2020, 07:35 and posted on 21.12.2020, 06:56 by Max J. Huelsey, Geng Sun, Bin Zhang, Yao Xu, Shipeng Ding, Sie Shing Wong, Ying Zheng, Shinya Furukawa, Hiroyuki Asakura, Yongqiang Cheng, Zili Wu, Rui Si, Ding Ma, Philippe Sautet, Ning Yan
Single-atom catalysts usually comprise positively charged atomically dispersed metal cations on oxide supports. Neutral atoms on oxides are synthetically challenging, and their performance in catalytic reactions remains ambiguous. Here, we shed light on this question with the design of Pd single-atom catalysts on polyoxometalates. Depending on the composition of the support, Pd can either exhibit oxidation states of 0 or 2+. We show that this difference is decisive for the C-O bond hydrogenolysis while displaying negligible effects on the C=O bond hydrogenation. The selective conversion of 5-hydroxymethylfurfural (5-HMF) to 2,5-dimethylfuran (2,5-DMF), a key renewable fuel compound, was shown to occur at 253 K with reaction rates up to 71.0 per hour.

History

Email Address of Submitting Author

m.huelsey@u.nus.edu

Institution

National University of Singapore

Country

Singapore

ORCID For Submitting Author

0000-0002-9894-0492

Declaration of Conflict of Interest

None

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