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Visible Light-Promoted Catalytic Ring-Opening Isomerization of 1,2-Disubstituted Cyclopropanols to Linear Ketones

preprint
submitted on 27.12.2019 and posted on 31.12.2019 by Marharyta V. Laktsevich-Iskryk, Nastassia A. Varabyeva, Volha V. Kazlova, Vladimir N. Zhabinskii, Vladimir A. Khripach, Alaksiej Hurski
In this article, we report a photocatalytic protocol for the isomerization of 1,2-disubstituted cyclopropanols to linear ketones. The reaction proceeds via radical intermediates and tolerates various functional groups.

History

Email Address of Submitting Author

ahurski@iboch.by

Institution

Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus

Country

Belarus

ORCID For Submitting Author

0000-0002-8599-2621

Declaration of Conflict of Interest

no conflict of interest

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