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Uranyl Speciation in the Presence of Specific Ion Gradients at the Electrolyte/Organic Interface

preprint
submitted on 14.04.2021, 17:45 and posted on 15.04.2021, 10:07 by Nitesh Kumar, Michael J. Servis, Aurora Clark

Uranyl (UO22+) speciation at the liquid/liquid interface is an essential aspect of the mechanism that underlies its extraction as part of spent nuclear fuel reprocessing schemes and environmental remediation of contaminated legacy waste sites. Of particular importance is a detailed perspective of how changing ion concentrations at the liquid interface alter the distribution of hydrated uranyl ion and its interactions with complexing electrolyte counterions relative to the bulk aqueous solution. In this work, classical molecular dynamics simulations have examined uranyl in bulk LiNO3(aq) and in the presence of a hexane interface. UO22+ is observed to have both direct coordination with NO3- and outer-sphere interactions via solvent-separated ion-pairing (SSIP), whereas the interaction of Li+ with NO3- (if it occurs) is predominantly as a contact ion-pair (CIP). The variability of uranyl interactions with nitrate is hypothesized to prevent dehydration of uranyl at the interface, and as such the cation concentration is unperturbed in the interfacial region. However, Li+ loses waters of solvation when it is present in the interfacial region, an unfavorable process that causes a Li+ depletion region. Although significant perturbations to ion-ion interactions, solvation, and solvation dynamics are observed in the interfacial region, importantly, this does not change the association constants of uranyl with nitrate. Thus, the experimental association constants, in combination with knowledge of the interfacial ion concentrations, can be used to predict the distribution of interfacial uranyl nitrate complexes. The enhanced concentration of uranyl dinitrate at the interface, caused by excess adsorbed NO3-, is highly relevant to extractant ligand design principles as such nitrate complexes are the reactants in ligand complexation and extraction events.

Funding

Department of Energy, Basic Energy Sciences Separations program (DE-SC0001815)

History

Email Address of Submitting Author

nitesh.kumar@wsu.edu

Institution

Washington State University

Country

United States

ORCID For Submitting Author

http://orcid.org/0000-0003-3322-8450

Declaration of Conflict of Interest

None

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