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Tuning Iridium(I) PCcarbeneP Frameworks for Facile Cooperative N2O Reduction

preprint
revised on 10.07.2018 and posted on 10.07.2018 by Joel D. Smith, Edwina Chih, Warren Piers, Denis M. Spasyuk
A semiquantitative kinetic study correlates the rate of oxygen atom transfer from N2O to an iridium carbon double bond with the donor properties of six PCcarbeneP pincer ligand frameworks. Two new rigid, electron rich ligands are described and shown to be the most effective for rapid, selective reaction with N2O.

History

Email Address of Submitting Author

wpiers@ucalgary.ca

Institution

University of Calgary

Country

Canada

ORCID For Submitting Author

0000-0003-2278-1269

Declaration of Conflict of Interest

There is no conflict of interest

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