Total Synthesis and Structural Verification of Isatindigotindoline C

29 October 2019, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Total synthesis of the polycyclic alkaloid isatindigotindoline C is achieved in two steps using an exo-selective [3+2]-dipolar cycloaddition. The synthesis verifies the originally computationally assigned relative stereochemistry.

Keywords

Oxindole Alkaloids
Total Synthesis
Isatindigotindoline C
Dipolar Cycloadditions
Biomimetic Synthesis

Supplementary materials

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isatindigotindoline SI chemrxiv 251019
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