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Thermodynamics of Chemical and Electrochemical Stability of Fe – Ge System Alloys
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The standard Gibbs
energies of formation of intermatallides Fe6Ge5, FeGe,
FeGe2 were estimated. Thermodynamic properties of α- and β- solid metallic solutions of Fe – Ge
system and spinel solutions of Fe3O4 – Fe2GeO4
system were determined. The state diagram of Fe – Ge – O system and the
potential – рН diagram of Fe – Ge – H2O system at 25ºС were plotted.
The thermodynamic features of the corrosion-electrochemical behaviour of Fe –
Ge system was discussed