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The Use of Copper and Vanadium Mineral Ores in Catalyzed Mechanochemical Carbon–carbon Bond Formations

preprint
submitted on 18.03.2020 and posted on 19.03.2020 by Francesco Puccetti, Christian Schumacher, Hermann Wotruba, José G. Hernández, Carsten Bolm
Under mechanochemical conditions in ball mills, copper- and vanadium-containing minerals initiate atom transfer radical cyclizations and oxidative couplings, respectively. Only catalytic quantities of the minerals are required, and the reactions proceed either under neat conditions or in the presence of a minimal amount of solvent.

Funding

1) RWTH Aachen University. 2) The German Research Foundation (DFG; project BO 823/16-1). 3) Kekulé scholarship from Verband der Chemischen Industrie e.V.

History

Email Address of Submitting Author

Jose.Hernandez@oc.rwth-aachen.de

Institution

RWTH Aachen University

Country

Germany

ORCID For Submitting Author

0000-0001-9064-4456

Declaration of Conflict of Interest

none

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