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The Effects of Enhancing the Crosslinking Degree in High Internal Phase Emulsion Templated Poly(dicyclopentadiene) Cured by Ring-Opening Metathesis Polymerization by a Crosslinking Comonomer

preprint
submitted on 30.08.2019 and posted on 03.09.2019 by Efthymia Vakalopoulou, Christian Slugovc
The effect of enhancing the crosslinking degree in polyHIPEs made from dicyclopentadiene by additionally using a crosslinking comonomer is described. Foams of 80% porosity with 10-40 w% comonomer content in the continous phase are prepared and show similar porosities and morphological characteristics as foams prepared with dicyclopentadiene alone. Assessing the mechanical properties reveals that the ductility is decreasing while the stiffness of the samples is increasing with increasing comonomer content. The foams containing the crosslinking comonomer take up at least five fold mass of toluene therby swelling to at least 30 v%. Upon drying of the swollen specimens, their initial shap and porosity are recovered. This feature distinguishes them from polyHIPEs made from dicyclopentadiene only.

Funding

Lead-project LP-03 from Graz University of Technology

History

Email Address of Submitting Author

slugovc@tugraz.at

Institution

Graz University of Technology

Country

Austria

ORCID For Submitting Author

0000-0003-1873-5200

Declaration of Conflict of Interest

No competing interests.

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