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Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

preprint
submitted on 15.08.2019 and posted on 16.08.2019 by Swaraj Sengupta, Sahanwaj Khan, Shyamal K. Chattopadhyay, Indrani Banerjee, Tarun K. Panda, Subhendu Naskar
Synthesis and characterisation of one trinuclear copper complex, ([Cu3L3O]ClO4) (1) and one nickel complex ([Ni(L'H)2(dmso)2](ClO4)2) (2) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L'H). 1 shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. 2 shows phenoxazinone synthase activity.

History

Email Address of Submitting Author

ssg_bit76@yahoo.com

Institution

Birla Institute of Technology, Mesra

Country

India

ORCID For Submitting Author

0000-0001-6967-858X

Declaration of Conflict of Interest

There are no conflicts of interest to declare.

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