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Synthesis of Unsymmetrical Sulfamides and Polysulfamides Via SuFEx Click Chemistry

preprint
submitted on 07.07.2020, 16:18 and posted on 08.07.2020, 11:44 by Ryan Kulow, Jiun Wei Wu, Cheoljae Kim, Quentin Michaudel
In this manuscript, we report practical, robust, and efficient conditions to synthesize a variety of unsymmetrical sulfamides via Sulfur(VI) Fluoride Exchange (SuFEx) click chemistry. This SuFEx strategy was subsequently harnessed to prepare a broad array of polysulfamides through polycondensation. The generality of the conditions allowed the synthesis of polymers with diverse architectures.

Funding

The Welch Foundation (A- 2004-20190330)

History

Email Address of Submitting Author

quentin.michaudel@chem.tamu.edu

Institution

Texas A&m University

Country

USA

ORCID For Submitting Author

0000-0002-1791-9174

Declaration of Conflict of Interest

No conflict of interest.

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