Synthesis of Unsymmetrical Sulfamides and Polysulfamides Via SuFEx Click Chemistry

In this manuscript, we report practical, robust, and efficient conditions to synthesize a variety of unsymmetrical sulfamides via Sulfur(VI) Fluoride Exchange (SuFEx) click chemistry. This SuFEx strategy was subsequently harnessed to prepare a broad array of polysulfamides through polycondensation. The generality of the conditions allowed the synthesis of polymers with diverse architectures.