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Synthesis of Atomically Precise Single-Crystalline Ru2-Based Coordination Polymers

preprint
submitted on 24.06.2020 and posted on 26.06.2020 by Wen-Yang Gao, Gerard Van Trieste, David Powers
Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru2 metallomonomers via labile Ag–N bonds provides access to a family of atomically precise single-crystalline Ru2-based coordination polymers with varied network topology and primary coordination sphere.

Funding

U.S. Department of Energy DE-SC0018977

Welch Foundation A-1907

History

Email Address of Submitting Author

powers@chem.tamu.edu

Institution

Texas A&M University

Country

USA

ORCID For Submitting Author

0000-0003-3717-2001

Declaration of Conflict of Interest

No conflict of interest.

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