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MS_101320_ACSenergylett_merged.pdf (3.25 MB)

Synergistic Effect of Hydrogen Bonding and π-π Stacking Enables Long Cycle Life in Organic Electrode Materials

preprint
submitted on 19.11.2020, 12:40 and posted on 20.11.2020, 04:18 by Madison R. Tuttle, Shelby Davis, Shiyu Zhang
Small-molecule organic compounds have emerged as attractive candidates for energy storage in lithium-ion batteries due to their sustainability and modularity. To develop generalizable design principles for organic electrode materials (OEMs), we investigated the correlation between electrochemical performance and addition of functional groups that promote synergistic hydrogen bonding and π-π stacking using a series of quinone-fused aza-phenazines (QAPs) with different hydrogen bonding donor/acceptor arrays. The QAP containing the most hydrogen bonding groups (3) exhibits the best performance with discharge capacities of 145 mAh g-1 at 2C with 82% capacity retention over 1000 cycles. The performance of 3 is attributed to the strategically incorporated -OH and -NH2 groups, which facilitate strong intermolecular interactions and a tightly packed 2D structure. The intermolecular interaction strength was evaluated using variable temperature 1D 1H NMR and 2D 1H-1H NOESY, offering a new strategy to help understand and predict the performance of OEMs with hydrogen bonding motifs.

History

Email Address of Submitting Author

zhang.8941@osu.edu

Institution

Ohio State University

Country

United State

ORCID For Submitting Author

0000-0002-2536-4324

Declaration of Conflict of Interest

No conflict of interest

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