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Synchronizing Gas Injections and Time-Resolved Data Acquisition for Perturbation-Enhanced APXPS Experiments

preprint
submitted on 16.11.2020, 12:57 and posted on 17.11.2020, 06:18 by Evgeniy Redekop, Niclas Johansson, Esko Kokkonen, Samuli Urpelainen, Felipe Lopes da Silva, Unni Olsbye
An experimental approach is described in which well-defined perturbations of the gas feed into an Ambient Pressure X-Ray Photoelectron Spectroscopy (APXPS) cell are digitally synchronized with time-resolved XPS data acquisition with a Delay Line Detector (DLD). These experiments unlock new possibilities for investigating the properties of materials and chemical reactions mediated by their surfaces, such as those in heterogeneous catalysis, surface science, and coating/deposition applications. Implementation of this approach, which is termed perturbation-enhanced APXPS, at the SPECIES beamline of MAX-IV Laboratory is discussed along with several experimental examples including (1) individual pulses of N2 gas over Au foil, a multi-pulse titration of oxygen vacancies in a pre-reduced TiO2 single crystal with O2 gas, and a sequence of alternating precursor pulses for Atomic Layer Deposition (ALD) of TiO2 on a silicon wafer substrate.

Funding

Research Council of Norway, grant 272266

Interreg Öresun-Kattegat-Skagerrak ESS & MAX IV: Cross Border Science and Society, MAX4ESSFUN, Ref. no. MAX-004

European Research Council, grant 717022

Academy of Finland, grant 326291

History

Email Address of Submitting Author

evgeniyr@smn.uio.no

Institution

Centre for Materials Science and Nanotechnology (SMN), Department of Chemistry, University of Oslo

Country

Norway

ORCID For Submitting Author

0000-0001-6430-8811

Declaration of Conflict of Interest

The authors declare no conflicts of interest

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