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Supramolecular Behaviour and Fluorescence of Rhodamine-Functionalised ROMP Polymer

preprint
submitted on 31.05.2020 and posted on 02.06.2020 by Lee Birchall, Sara Shehata, Sean McCarthy, Helena J. Shepherd, Ewan Clark, Christopher Serpell, Stefano Biagini

Inherently fluorescent polymers are of interest in materials and medicine. We report a ring-opening metathesis polymerisation (ROMP) platform for creation of amphiphilic block copolymers in which one block is formed from rhodamine B-containing monomers. The polymers self-assemble into well-defined micelles which are able to sequester molecular dyes and further interact with them by energy transfer. Despite incorporating a cationic dye known to bind DNA, the polymer micelles do not interact with DNA, indicating that they are potentially safe for use in bioanalytical applications.

Funding

School of Physical Sciences, University of Kent Graduate Training Scheme, and by the EPSRC Doctoral Training Programme

History

Email Address of Submitting Author

s.biagini@kent.ac.uk

Institution

University of Kent

Country

United Kingdom

ORCID For Submitting Author

0000-0002-4713-5127

Declaration of Conflict of Interest

No conflict of interest

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