ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
Luoh-draft-joc-531.pdf (513.03 kB)

Sulfur Mediated Allylic C-H Arylation, Epoxidation and Aziridination

preprint
revised on 31.05.2019 and posted on 31.05.2019 by Hang Luo, Gang Hu, Pingfan Li
Transition-metal-free, sulfur mediated allylic C-H arylation, epoxidation and aziridination were realized through one-pot procedures. The reaction design involved initial addition between olefins and triflic anhydride activated sulfoxides, followed by subsequent reactions of the allylic sulfur ylides generated under basic conditions with arylboronic acids, aldehydes, or aldimines, to give allylic arylation, epoxidation or aziridination products, respectively.

Funding

National Natural Science Foundation of China (21402005)

Fundamental Research Funds for the Central Universities (XK-1802-6, 12060093063)

History

Email Address of Submitting Author

lipf@mail.buct.edu.cn

Institution

Beijing University of Chemical Technology

Country

China

ORCID For Submitting Author

0000-0002-0056-9243

Declaration of Conflict of Interest

no conflict of interest

Exports