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Sterically Controlled C‒H Olefination of Heteroarenes

preprint
submitted on 31.10.2019 and posted on 15.11.2019 by Hao Chen, Mirxan Farizyan, Francesca Ghiringhelli, Manuel van Gemmeren
We report a sterically controlled C–H olefination using heteroarenes as the limiting reagent. The method enables the highly C5-selective olefination of a wide range of heteroarenes and is shown to be useful in the context of late-stage functionalization.

Funding

Otto Hahn Award; Max Planck Gesellschaft

Liebig Fellowship; Verband der Chemischen Industrie

Doctoral Fellowship (Francesca Ghiringhelli); Studienstiftung des deutschen Volkes

WWU Münster

History

Email Address of Submitting Author

mvangemmeren@uni-muenster.de

Institution

Max Planck Institute for Chemical Energy Conversion and WWU Münster

Country

Germany

ORCID For Submitting Author

0000-0003-3080-3579

Declaration of Conflict of Interest

There is no conflict of interests.

Exports

Read the published paper

in Angewandte Chemie

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