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Squeezing Bi: PNP and P2N3 Pincer Complexes of Bismuth(III

preprint
submitted on 17.04.2020 and posted on 21.04.2020 by Marcus B. Kindervater, Toren Hynes, Katherine Marczenko, Saurabh Chitnis
We report the first application of a rigid P2N3 pincer ligand in p-block chemistry by preparing its bismuth complex. We also report the first example of bismuth complexes featuring a flexible PNP pincer ligand, which shows phase-dependent structural dynamics. Highly electrophilic, albeit thermally unstable, Bi(III) complexes of the PNP ligand were also prepared.

History

Email Address of Submitting Author

saurabh.chitnis@dal.ca

Institution

Dalhousie University

Country

Canada

ORCID For Submitting Author

0000-0001-9180-7907

Declaration of Conflict of Interest

None

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