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Selective CO2 Sorption Using a Compartmentalized Coordination Polymer with Discrete Voids

preprint
submitted on 27.05.2020 and posted on 29.05.2020 by Eugenia Miguel-Casañ, Eduardo Andres-Garcia, Joaquin Calbo, Dr. Mónica Giménez Marqués, Guillermo Minguez Espallargas
We report a novel Fe(II) compartmentalized coordination polymer (CCP) capable of physisorbing gas molecules in a selective manner. The crystal structure was modelled theoretically under the Density Functional Theory revealing the presence of discrete voids of 380 Å3, significantly larger than those reported for its predecesors. Adsorption isotherms of pure N2, CH4 and CO2 were measured, obtaining a loading capacity of 0.6, 1.7 and 2.2 molecules/void at 10 bar and at 298 K. Dynamic breakthrough gas experiments have been performed at different fluxes and temperatures, showing efficient adsorption and excellent selectivities for CO2 in gas mixtures with methane and nitrogen.

History

Email Address of Submitting Author

guillermo.minguez@uv.es

Institution

University of Valencia, ICMol

Country

Spain

ORCID For Submitting Author

0000-0001-7855-1003

Declaration of Conflict of Interest

no conflict of interest

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