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V2_The_MM_H2_article_manuscript.pdf (1.23 MB)

The Profound Unravelling of Equilibrium Thermodynamics and Arrhenius First-Order Kinetics in Relation to Metal Hydride Desorption Reactions

preprint
revised on 24.01.2021, 23:14 and posted on 27.01.2021, 09:13 by Roland Hermann Pawelke

Approaching the entanglement problem of kinetics with thermodynamics in reversible metal hydride desorption reactions by means of a hyperbola template such as the Michaelis-Menten curve renders a closed solution for their unravelling possible, revealing profound insight of general significance into both, the structure of the rate-limiting thermodynamic factor and the nature of experiment-specific first-order Arrhenius kinetics. As by-product an alternate method of extreme simplicity for modelling transient behaviour of reversible metal hydride tanks is obtained. This paper concludes a series of works concerned with objectively approaching metal hydride soprtion reaction kinetics.

Funding

European Space Agency grant 4000105330/12/NL/CLP

History

Email Address of Submitting Author

roland.pawelke@hushmail.com

Institution

FOTEC Forschungs- und Technologietransfer GmbH

Country

Austria

ORCID For Submitting Author

0000-0002-6944-2240

Declaration of Conflict of Interest

There are no conflicts to declare.

Version Notes

V2: The paper has been given a revision and a different emphasis: it is less about actual tank modelling but the complete objective untangling of first-order kinetics and equilibrium thermodynamics ensuing from this approach, which is quite awesome. The title has changed accordingly.

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