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Seawater Electrolysis for Hydrogen Production: A Solution Looking for a Problem?

submitted on 01.03.2021, 23:39 and posted on 09.03.2021, 04:42 by Md Kibria, Mohd Adnan Khan, Tareq A. Al-Attas, Soumyabrata Roy, M.M. Rahman, NorEddine Ghaffour, Venkataraman Thangadurai, Steve Larter, Jinhuang Hu, Pulickel Ajayan
As the price of renewable electricity continues to plummet, hydrogen (H2) production via water electrolysis is gaining momentum globally as a route to decarbonize our energy systems. The requirement of high purity water for electrolysis as well as the widespread availability of seawater have led significant research efforts in developing direct seawater electrolysis technology for H2 production. In this Perspective, we critically assess the broad-brush arguments on the research and development (R&D) needs for direct seawater electrolysis from energy, cost and environmental aspects. We focus in particular on a process consisting of sea water reverse osmosis (SWRO) coupled to proton exchange membrane (PEM) electrolysis. Our analysis reveals there are limited economic and environmental incentives of pursuing R&D on today’s nascent direct seawater electrolysis technology. As commercial water electrolysis requires significant amount of energy compared to SWRO, the capital and operating costs of SWRO are found to be negligible. This leads to an insignificant increase in levelized cost of H2 (<0.1 $/kg H2) and CO2 emissions (<0.1%) from a SWRO-PEM coupled process. Our analysis poses the questions: what is the future promise of direct seawater electrolysis? With an urgent need to decarbonize our energy systems, should we consider realigning our research investments? We conclude with a forward-looking perspective on future R&D priorities in desalination and electrolysis technologies.


Canada First Research Excellence Fund


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University of Calgary



ORCID For Submitting Author

Declaration of Conflict of Interest

No conflict of interest

Version Notes

First version of the manuscript