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Robust Photopatterning of Gold-Thiol Self-Assembled Monolayers

preprint
submitted on 31.07.2019 and posted on 01.08.2019 by Nathaniel Miller, Geoffrey Hutchison
While photopatterning is in widespread use for patterning inorganic semiconductors, patterning of widely-used gold-thiol organic self-assembled monolayers is typically done with contact methods. Through common atomic force microscope techniques and quantification of the energy impinging on the target surface, the energy required for UV-photooxidation of Au-Thiol SAMs can be determined. This quantification allows for the precise control of features using simple shadow masking from electron microscopy grids or other targets. Beyond characterizing the accuracy and resolution of features, the pattern stability of the resulting monolayers is examined indicating a drive toward phase segregation and increasing order of the mixed monolayers.

Funding

National Science Foundation DMR-1608725

History

Email Address of Submitting Author

geoffh@pitt.edu

Institution

University of Pittsburgh, Department of Chemistry

Country

United States of America

ORCID For Submitting Author

0000-0002-1757-1980

Declaration of Conflict of Interest

No conflict of interest

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