These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
2 files

Revealing the reactivity of the Iridium trioxide intermediate for the oxygen evolution reaction in acidic media

submitted on 25.04.2019, 12:43 and posted on 29.04.2019, 18:11 by Paul Pearce, Chunzhen Yang, Antonella Iadecola, Juan Rodriguez-Carvajal, Gwenaëlle Rousse, Rémi Dedryvère, Artem M. Abakumov, Domitille Giaume, Michael Deschamps, Jean-Marie Tarascon, Alexis Grimaud
We report a strategy to isolate IrO3 as an intermediate for the oxygen evolution reaction (OER). Its reactivity is studied using X-ray absorption spectroscopy, X-ray and neutron diffraction and X-ray photoelectron spectroscopy. Its stability is assessed by using on-line mass spectroscopy and inductively coupled plasma optical emission spectroscopy and presented herein. Upon reaction with water in acidic conditions, we could observe the formation of a new protonated iridate phase of composition H2IrO3. Coupling OER measurements and dissolution rate determination, we could show that its activity and stability are governed by a yet ill-described charge compensation mechanism enlisting reversible bulk proton insertion inside the catalyst structure. This singular property enables an enhanced activity and stability towards dissolution compared to the stellar IrOx/SrIrO3 catalyst. Such a finding opens the route towards the design of new OER catalysts enlisting proton insertion that could be competitive for water splitting in acidic media.


ERC Grant-Project 670116-ARPEMA


Email Address of Submitting Author


Collège de France



ORCID For Submitting Author


Declaration of Conflict of Interest

There are no conflicts to declare.