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Resorcin[4]arene-Based Multidentate Phosphate Ligands with Superior Binding Affinity for Nanocrystal Surfaces

preprint
submitted on 13.01.2021, 10:52 and posted on 13.01.2021, 13:33 by Suren J. Nemat, Loren Deblock, Dietger Van den Eynden, Michael Heilmann, Jesper Köster, Konrad Tiefenbacher, Jonathan De Roo
We designed and synthesized two resorcin[4]arene scaffolds with four phosphoric acid binding groups. The ligands effectively bind in at least a tridentate fashion. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of phosphonic acids.

Funding

SNF NCCR molecular systems engineering (SNF project number: 182895)

History

Email Address of Submitting Author

jonathan.deroo@unibas.ch

Institution

University of Basel

Country

Switzerland

ORCID For Submitting Author

0000-0002-1264-9312

Declaration of Conflict of Interest

No conflict of interest

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