These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
Regioselective Gas-Phase n-Butane Transfer Dehydrogenation via Silica-Supported Pincer-Iridium Complexes
preprintsubmitted on 28.08.2020, 00:37 and posted on 28.08.2020, 10:54 by Boris Sheludko, Cristina Castro, Chaitanya Khalap, Thomas Emge, Alan Goldman, Fuat E. Celik
Abstract: The production of olefins via on-purpose dehydrogenation of alkanes allows for a more efficient, selective and lower cost alternative to processes such as steam cracking. Silica-supported pincer-iridium complexes of the form [(≡SiO-R4POCOP)Ir(CO)] (R4POCOP = κ3-C6H3-2,6-(OPR2)2) are effective for acceptorless alkane dehydrogenation, and have been shown stable up to 300 °C. However, while solution-phase analogues of such species have demonstrated high regioselectivity for terminal olefin production under transfer dehydrogenation conditions at or below 240 °C, in open systems at 300 °C, regioselectivity under acceptorless dehydrogenation conditions is consistently low. In this work, complexes [(≡SiO-tBu4POCOP)Ir(CO)] (1) and [(≡SiO-iPr4PCP)Ir(CO)] (2) were synthesized via immobilization of molecular precursors. These complexes were used for gas-phase butane transfer dehydrogenation using increasingly sterically demanding olefins, resulting in observed selectivities of up to 77%. The results indicate that the active site is conserved upon immobilization.
Read the published paper
First-Principles Design of Coke-Resistant Dehydrogenation Catalysts for Valorization of Light Hydrocarbon Feedstocks
Directorate for EngineeringFind out more...
Alkane Transformations based on Dehydrogenation and Related Reactions: A Tandem Approach
Basic Energy SciencesFind out more...