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Redox Polymers Incorporating Pendant 6-Oxoverdazyl and Nitronyl Nitroxide Radicals

preprint
revised on 23.10.2019 and posted on 23.10.2019 by Michael Anghel, Francois Magnan, Sara D. Catingan, Matthew A. McCready, Elaheh Aawani, Victor Wong, Deepa Singh, Giovanni Fanchini, Joe Gilroy
Polymers comprised of redox-active organic radicals have emerged as promising materials for use in a variety of organic electronics, including fast-charging batteries. Despite these advances, relatively little attention has been focused on the diversification of the families of radicals that are commonly incorporated into polymer frameworks, with most radical polymers being comprised of nitroxide radicals. Here, we report two new examples prepared via ring-opening methathesis polymerization containing 6-oxoverdazyl and nitronyl nitroxide radicals appended to their backbones. The polymerization reaction and optoelectronic properties were explored in detail, revealing high radical content and redox activity that may be advantageous for their use as semiconducting thin films. Initial studies revealed that current-voltage curves obtained from thin films of the title polymers exhibited memory effects making them excellent candidates for use in resistive memory applications.

Funding

NSERC: SPG-P, 506356-2017

Ontario Ministry for Research and Innovation: ERA, ER-14-10-147

Canadian Foundation for Innovation: JELF, 33977

History

Email Address of Submitting Author

joe.gilroy@uwo.ca

Institution

Department of Chemistry, The University of Western Ontario

Country

Canada

ORCID For Submitting Author

0000-0003-0349-7780

Declaration of Conflict of Interest

No conflict of interest

Version Notes

version 1.0

Exports