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Predicting Low Toxicity and Scalable Solvent Systems for High Speed Roll-to-Roll Perovskite Manufacturing

preprint
submitted on 11.11.2020, 15:56 and posted on 12.11.2020, 13:15 by Richard Swartwout, Rahul Patidir, Emma Belliveau, Benjia Dou, David Beynon, Peter Greenwood, Nicole Moody, Dane W. deQuilettes, Moungi Bawendi, Trystan M. Watson, Vladimir Bulovic
This manuscript introduces solvent toxicity in solar perovskite ink chemistries as a major technoeconomic limitation for the growth of the technology. More specifically, the capital and operational cost of handling such toxic chemicals to maintain a safe working environment can lead to significant added costs. As all record power conversion efficiency devices to date have been solution processed, this represents a major challenge for the perovskite optoelectronic field and of printed electronics as a whole. Knowing this limitation, we propose that solvent selections for ink chemistries should be more quantitative and focus on lowering toxicity. To this end, we show that a Hansen solubility model is effective in predicting ink systems using lower toxicity solvents. We also show that inks formed from this method are applicable for high-speed slot-die coating, limiting the need for long anneal times. These methods and results demonstrate a useful framework for quantitatively engineering solvent systems with reduced toxicity while simultaneously maintaining and surpassing performance. It therefore provides a pathway and major step forward towards the commercialization of solution coated perovskite technologies.

Funding

European Union Horizon 2020

Marie Sklodowska—Curie grant agreement No 764787

European Regional Development Fund through the Welsh Government

Engineering and Physical Sciences Research Council (EPSRC) through the SPECIFIC Innovation and Knowledge Centre (EP/N020863/1).

History

Email Address of Submitting Author

swartr@mit.edu

Institution

MIT

Country

United States

ORCID For Submitting Author

0000-0003-1603-3491

Declaration of Conflict of Interest

None

Version Notes

Initial Submission

Exports