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Ahmad Masarwa chemrxiv Dec.2019 A.pdf (1.03 MB)

Photoredox of Gem-Diborylalkenes: A Novel Reactivity Toward Diverse 1,1-Bisborylalkanes

preprint
submitted on 17.12.2019, 14:31 and posted on 23.12.2019, 20:18 by Nivesh Kumar, Nadim Eghbarieh, Tamar Stein, Alexander Shames, Ahmad Masarwa
The use of gem-bis-metalated-alkenes, i.e., vinyl gemdiboron-compound, as light-labile substrates is explored for the first time. The knowledge gained provided us with an in-depth understanding of the reactivity of novel radical intermediates of geminal-metalated ethane. This methodology can serve as the late-stage diversification of bioactive molecules and simple organic molecules in which it drives the synthesis of gemdiborylalkanes.

History

Email Address of Submitting Author

Ahmad.Masarwa1@mail.huji.ac.il

Institution

The Hebrew University of Jerusalem

Country

Israel

ORCID For Submitting Author

0000-0001-6992-5595

Declaration of Conflict of Interest

no conflict of interest

Version Notes

This is not the last version

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ChemRxiv

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