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A Bench-Stable Catalyst for the Rapid Hydrophosphination of Activated and Unactivated Alkenes

preprint
revised on 01.10.2020 and posted on 05.10.2020 by Steven Dannenberg, Rory Waterman
Cu(acac)2 (1) is a highly active catalyst for the hydrophosphination of alkenes. Photocatalytic conditions are critical, which provde high conversions with unactivated substrates that have never before been reported with an air-stable catalyst or at ambient temperature. The simplicity of compound 1 places hydrophosphination in the hands of more synthetic chemists.

Funding

NSF CHE-1565658

NASA Cooperative Agreement NNX15AP86H

History

Email Address of Submitting Author

rory.waterman@uvm.edu

Institution

University of Vermont

Country

United States

ORCID For Submitting Author

0000-0001-8761-8759

Declaration of Conflict of Interest

none

Version Notes

pre-submission text

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