ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
1/1
0/0

Palladium-Catalyzed 2-(Neopentylsulfinyl)aniline Directed C-H Acetoxylation and Alkenylation of the Arylacetamides

preprint
submitted on 06.09.2019 and posted on 09.09.2019 by Maryia V. Barysevich, Marharyta V. Laktsevich-Iskryk, Anastasiya V. Krech, Vladimir N. Zhabinskii, Vladimir A. Khripach, Alaksiej Hurski
A directing group that promotes very fast diacetoxylation of the arylacetamides is reported. The auxiliary also promotes alkenylation with vinyl ketones, which were generated in one-pot from the cyclopropanols.

Funding

Belarusian Foundation for Fundamental Research (project X17-073)

History

Email Address of Submitting Author

ahurski@iboch.by

Institution

Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus

Country

Belarus

ORCID For Submitting Author

0000-0002-8599-2621

Declaration of Conflict of Interest

no conflict of interest

Exports

Logo branding

Exports