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Organic Photoredox-Catalyzed Cycloadditions Under Single-Chain Polymer Confinement

preprint
submitted on 07.07.2020 and posted on 08.07.2020 by Jacob Piane, Lauren Chamberlain, Lucas T. Alameda, Ashley Hoover, Elizabeth Elacqua
Cooperative catalysis enables synthetic transformations that are not feasible using monocatalytic systems. Such reactions are often diffusion controlled and require multiple catalyst interactions at high dilution. We developed a confined dual-catalytic polymer nanoreactor that enforces catalyst co-localization to enhance reactivity in a fully-homogeneous system. The photocatalyzed-dimerization of substituted styrenes is disclosed using confined-single-chain polymers bearing triarylpyrylium-based pendants, with pyrene as an electron relay catalyst. Enhanced reactivity with low catalyst loadings was observed compared to monocatalytic polymers with small-molecule additives. Our approach realizes a dual-catalytic single-chain polymer that provides enhanced reactivity under confinement, presenting a further approach for diffusion-limited-photoredox catalysis.

History

Email Address of Submitting Author

elizabeth.elacqua@psu.edu

Institution

The Pennsylvania State University

Country

United States

ORCID For Submitting Author

0000-0002-1239-9560

Declaration of Conflict of Interest

There are no conflicts of interest.

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