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Orbital Phase Perspective of Goodenough-Kanamori-Anderson Rules (GKA Rules) in Superexchange Interaction

preprint
revised on 11.06.2020, 02:19 and posted on 12.06.2020, 09:43 by Yuji Naruse, Atsushi Takamori
Goodenough-Kanamori-Anderson rules (GKA rules) in superexchange interaction discriminate the magnetic properties of two magnetic metal ions bridged with an anion. We propose here that the GKA rules can be explained in terms of the orbital phase continuity-discontinuity property of cyclic orbital interaction including direct metal-metal orbital interaction.

Funding

This research was funded by Gifu University.

History

Email Address of Submitting Author

naruse@gifu-u.ac.jp

Institution

Gifu University

Country

Japan

ORCID For Submitting Author

0000-0003-3910-9356

Declaration of Conflict of Interest

There is no conflict of interest.

Version Notes

ver. 2.1 in current acs format

Exports